Simon is quite right
Generally, the turning for performance (within limits obviously) is precisely the same as tuning for economy; the two go hand-in-hand. The goal in both instances being to make the engine run as efficiently as possible for a given amount of fuel. So, if you have a well tuned engine and use it gently it'll be economical. It just takes restraint and cultivating a feather foot on the accelerator and learning the techniques of driving for economy.
Unfortunately, there is no magic ECU tweak that will improve economy drastically.
In the final analysis, good maintenance of the engine and drive-train, ensuring the brakes are not binding, tyre pressures, tracking and not carrying excess weight around make a far bigger difference to economy than any ECU tweaking might.
Try Shell V Power petrol or similar. More expensive I know but the higher octane allows the engine to run with more ignition advance before the knock sensor activates and thus more efficiently. It makes a noticable difference in my Activa.