There is a YouTube video on: Peugeot 207cc boot wont open ... that shows a method of getting the boot open but it involves cutting an opening in the boot lining. And avoiding destroying the bar for the blind. Pretty desperate really.
I also note that Peugeot forums had a similar entry: 307cc Boot stuck shut!
"Solution!
There is a flappy plastic part behind the rear seat head rests.
I used 2 small screwdriver handles to wedge it up in the middle and stay there. Now i can see the boot lock using a good flashlight.
There is a small hole on the left side of the lock box to release the mechanism.
I made a 1.3 m long small screwdriver using a threaded bar m10 that i grinded to about 3 mm diameter in the end. Put it in the hole and press to the left and the boot popped up!

No damage to the car."
Boot opening button in the 0 of the 307 badge
Just had the Same! Keys locked in the boot. But found by chance there is a boot opening button in the 0 of the 307 on the boot!!!
Press this and the boot will open!
The 307 hatch had a very poorly designed wiring loom to the boot that was prone to breaking the wires leading to the boot lid. I don't know if this poor bit of design carried over to the CC but it would be worth checking the loom where it flexes near the boot once you have the boot lid open.