Something odd going on there...
On the 'new' hub the centre part looks smaller diameter? In which case it will be no good for you, as the wheel won't fit properly. Also, if you put that hub in your hub carrier, then it will probably still be in the same (wrong!) place. If you look at the back of the bearing, is the hub flush with the back of the bearing?
You can't change the hub without changing the bearing - when you pull the hub out of the bearing it will pull the inner part of the outer race of the bearing with it (and which you will then need to cut / press off the hub), rendering the bearing scrap.
I've got one of those tool sets, and used it to change both front wheel bearings on my 307. It works surprisingly well, but you need a big vice to hold the hub, and a bag bar to turn the nut on the screw (see that breaker bar you used to get the hub nut undone

). What I did with mine was to put tension on the bearing, then support the hub and give the end of the tool a good few whacks - this was enough to just unseat the bearing, and allow me then to pull it out. First of course you need to remove the circlip on the back - and that may be a whole world of pain!
Easiest way to get the hub out of the bearing is to get a couple of bolts the same pitch as the wheel bolts, and then screw them through the wheel bolt holes, and using appropriate packers, use them to jack the hub out of the bearing / carrier (some of the tool sets contain screws that are for this, but be aware that PSA sometimes use different thread pitch, so the std ones may not be any good (I got to having all the bolts undone and ready to take the hub carrier off the car before I realised that....

)