Ive noticed with most C5s ive had that with the climate set to the desired temp after a while the temperature fluctuates, usually getting colder. I had thought this was to do with the flaps not working properly, but im not so sure now?
Is this actually the case, or a subjective impression? There will undoubtedly be some fluctuation due to hysteresis in the control system, but that should not be noticeable. I wonder if it's more a case that one appreciates the nice warm air initially, then gets used to it; as the set temperature is reached, the system reduces the temperature of the airflow to stabilise the cabin temp, which is then perceived as a cooling effect. The best way to check would be with a digital (for fast response) thermometer.
Bear in mind, though, that Citroen specifically state that the displayed settings are not intended to represent temperatures, but 'comfort levels', which sounds to me a bit like a getout!