The clues:
The coolant is under more pressure than my last Xantia. It also sounds like it's mildly venting through the pressure relief valve cap. The temp sender generally reads 70degrees while driving above 20/30mph. Left to idle it will slowly move up to about 89 and if pushed, go to about 99 where the fan brings it straight down again. The driver's footwell is damp-sodden underneath. While the radiator is new and the cabin heating works. Any ideas what it could be, what to check for?