I've just overhauled the braking system on my C5, including new rear pads. I really wanted to take the rear discs off to clean/examine them as well. OK, so even with the pads out, you can't wangle the disc off with the caliper still in place. The two bolts that pass through the caliper body were partly corroded in place; alloy, steel, and road salt don't make a good mix. Anyhow, after masses of penetrating oil, and beating seven bells out of them with an impact driver, they did start to move.
So far so good, but as I slackened them off, I could see hydraulic fluid starting to leak out along the centre line of said caliper. From this I am assuming that the bolts that hold the caliper in place also clamp the two halves together, which seems a stupid idea to me. How do you get the calipers off without them falling in half, or don't you. ??
ISTR the same applies to the Xantia, though on my old BX you could get the disc out with the caliper still in place

Regards
Philip