Give this a try http://www.nvu.com/ its a free web page creator, looks like a cut down of dreamweaver. but even before all that the best place to start is a design a piece of paper with post it notes as your links and a good HTML book, always learn the code before using one of these flashy design progs.
The main thing you have to get your head round is that web publishing is very different from desktop publishing, i.e things have to be put in a uniform manner.
Once a home/index page is created you can then just expand on the theme.
Good shout on getting the domain name sorted, would be happy to help on getting the site up and running.