C5s and Xantias have a recognised fault with the rear calipers - corrosion occurs in the interface between the caliper and the radius arm and pushes the caliper out of alignment causing rapid and uneven wear of the pads and the disk,
There are several threads detailing the remedy - basically remove th caliper, clean the corrosion of the caliper and radius arm and refit with either a thin gasket to prevent contact between the two or grease the surfaces for the same effect. New pads will be needed if they are worn, possibly discs too.
They can be very difficult to remove!
Take the wheels off and check the pads for wearing in a wedge-shape.
C5 handbrake operates on the front wheels, not the rears.
Your MPG is poor, mine is crap at 32mpg round town, about 45 on longish runs (just done 599 miles average 42.5 mpg.)
Don't rely on the onboard computer, they are inaccurate and generally optimistic - mine doesn't work at all
Welcome to the forums, hope we can help you with your C5
