To remove the nut holding on the rear drums, you must first nip off the staking where the nut should have been peened. If you try to remove the nut, you can shear the stub axle, if you are using a socket and long bar.
If you have access to an air gun, you can get the nut off without removing the staking.
Once the nut & washer are off, you can access the self adjusters through the rear brake plate to wind back the adjusting bar. Look through the archive here as it has been written up before.
Once the adjusters and shoes are relieved,

, the hub will easily come off. There is no need for brute force ( Malcolm!!!)

.
Watch out for the brake dust, as it may contain asbestos. Always wise to wear a mask.
Check the shoes for wear, on 91K they may well be done for. Check also the seals in the cylinders by just lifting the rubber covers. Any fluid leaks and you will need new seals or cylinders. If you need to change the cylinders, on that mileage, you may need to be concerned about the brake pipes as they will be reluctant to come off.
Buy new nuts for the stub axles, about 90p plus VAT from Citroen. Maybe also worth replacing the grease seal on the inside of the hub and a new cap, if it is damaged.
Handyman