there have been loads of posts on here about psa diesels smoking on first start - up in the morning generaly considered to be as a result of air in the fuel line....
Ive changed all leak off pipes and all fuel pipe under the bonnet leaving the metal pipe under the car as the last suspect place for letting air in.
i changed the metal under car fuel pipe yesterday with one from citroen (£18 ) . It will be interesting to see if it is cured this morning. if it stops mine smoking - try it on yours!!
alastair