However in the process of driving in the heat I remembered the air conditioning doesn't seem to be working. I put the Lexia on the car and confirmed that there is zero drop in reported evaporator temperature when the compressor is running.

This is really frustrating and upsetting to be honest. It had a new compressor in March 2020 after the old one snapped a shaft and was re-gassed - all up around £500 and the aircon has worked brilliantly since then and as far as I know was still working fine before the car went off the road in December with the leaky heater matrix.
The confusing thing is that the compressor does still switch on, meaning the pressure switch is detecting sufficient pressure in the system, and the evaporator in the heater box assembly makes the usual "whoosh" noise when you first turn it on. You can also see plenty of activity in the site glass:
And yet zero cooling. Also the supply and return pipes to the compressor don't get hot or cold - they just stay at ambient.
What the heck could have happened ? Could sitting for 6 months without use have caused a problem ?
Could I have caused a leak when I pulled the aircon box forward a few inches in the cabin to free the heater box, which would have put some strain on the pipes where they enter through the firewall ? If so why is there still enough pressure to operate the pressure switch ?
Could I have damaged the evaporator ? I don't see how though ?
Is there any ducting that might have caused the airflow not to go through the evaporator or does it always pass through it ?
I'm mystified.
The problems and repair costs are racking up rapidly here to the point where I'm back to seriously wondering whether to throw the towel in. My other half keeps telling me I need to get rid of the car and it's becoming harder and harder to defend it to be honest. In the space of a couple of years it seems to have gone from a going concern to a "project car", one that hardly gets driven, has a lot of faults that need repairing, and will soon be legislated off the road in Glasgow. (Low emissions zones)
Between an excess payment for the windscreen replacement, possible re-gassing of the aircon, the new accumulator and anti-sink sphere, possibly some work on the rear brakes I'm probably looking at as much money as I bought the car for years ago.

I also have a right lower suspension arm to replace before the MOT as one of the bushes is stuffed, (although I do already have the arm) and I'm rapidly running out of time to do all these things before the MOT is due due to family commitments and weather.
For the first time with this car I feel like I'm paddling to try and stay afloat but there is just too much wrong with it and too much work that needs doing to get it back into a good working state. That's not even counting minor things like the fact that the radio doesn't work anymore.